Jennifer divorced Brad after five years of marriage in 2005, a year after ending Friends.
The ending of their marriage coincided with Pitt meeting Angelina Jolie on the set of Mr And Mrs Smith, prompting rumors to swirl that he had stepped out on Jennifer.
Jennifer subsequently starred opposite Vince Vaughn in The Break-Up, which followed a newly split up couple battling it out for the condo they shared during their relationship.

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